Copyright © 2001 Elsevier Science B.V. All rights reserved. In particular, the increase in the dielectric constant due to ion pairing and its decrease due to the presence of ions and their solvation can be accurately represented. Dielectric constant (ε): A measure of a substance's ability to insulate charges from each other. 65, 2065–2070 (1961), Dannhauser, W., Bahe, L.W. Technol. For most solvent mixtures, dielectric constants can be reasonably predicted using only pure solvent properties. © 2020 Springer Nature Switzerland AG. J. Chem. Abstract The dielectric constants (relative permittivities) of water, methanol, ethanol, bu-tanol and acetone were measured at 91.3 kPa and (283.15 and 293.15) K and are reported here. Fluid Phase Equil. Meas. Rev. NBS Circular No. 28, 575–592 (1999), Sivasubramanian, S., Widom, A., Srivastava, Y.N. Int. ): CRC Handbook of Electrical Filters. Part of Springer Nature. This is a preview of subscription content, log in to check access. 16, 929–955 (1995), Article Faraday Soc. Solution Chem. : Mechanism and Theory in Organic Chemistry, 3d edn. CRC Press, Boca Raton (1997), Garland, C.W., Niber, J.W., Shomaker, D.: Experiment in Physical Chemistry, 7th edn. J. Phys. 54, 4125–4139 (1932), Archer, D.G., Wang, P.: The dielectric constant of water and Debye–Hückel limiting law slopes. 12, 40–42 (1977), Article Data 19, 371–411 (1990), Owen, B.B., Miller, R.C., Milner, C.E., Cogan, H.L. volume 39, pages701–708(2010)Cite this article. Am. McGraw-Hill, Boston (2003), Gregory, A.P., Clarke, R.N. Parts I and II. Int. Journal of Chemical Education 1997 , 74 (5) , 556. PubMed Google Scholar. Technol. Data 19, 371–411 (1990), Owen, B.B., Miller, R.C., Milner, C.E., Cogan, H.L. 34, 38–41 (2004), Hamelin, J., Mehl, J.B., Moldover, M.R. : Dielectric Properties of Binary Solutions. CAS J. (eds. Relative permittivity is the ratio of "the permittivity of a substance to the permittivity of space or vacuum".. Meas. : The dielectric constant of water as a function of temperature and pressure. 34, 38–41 (2004), Hamelin, J., Mehl, J.B., Moldover, M.R. Tax calculation will be finalised during checkout. 186, 103–122 (2001), Hasted, J.B., Ritson, D.M., Collie, C.H. Mohsen-Nia, M., Amiri, H. & Jazi, B. Dielectric Constants of Water, Methanol, Ethanol, Butanol and Acetone: Measurement and Computational Study. Copyright © 2020 Elsevier B.V. or its licensors or contributors. For example, for the ethanol–water mixtures at 80°C , dielectric constant data for liquid ethanol do not exist. volume 39, pages701–708(2010)Cite this article. Ref. 54, 4125–4139 (1932), Archer, D.G., Wang, P.: The dielectric constant of water and Debye–Hückel limiting law slopes. Instrum. J. Thermophys. Phys. J. Google Scholar, Fernandez, D.P., Goodwin, A.R.H., Levelt Sengers, J.M.H. Google Scholar, Goodwin, R.H., Mehl, J.B., Moldover, M.R. J. Chem. Immediate online access to all issues from 2019. The dielectric constants were determined by using a new setup based on a low-pass ﬁlter. J. Phys. : Handbook of Chemistry and Physics, 85th edn. Journal of Solution Chemistry J. Chem. J Solution Chem 39, 701–708 (2010). © 2020 Springer Nature Switzerland AG. CAS Learn more about Institutional subscriptions, Jennings, S.G.: A method of measurement of the dielectric constant of some liquids. : Measurements of the relative permittivity of liquid water at frequencies in the range of 0.1 to 10 kHz and at temperatures between 273.1 and 373.2 K at ambient. https://doi.org/10.1007/s10953-010-9538-5, DOI: https://doi.org/10.1007/s10953-010-9538-5, Over 10 million scientific documents at your fingertips, Not logged in The comparisons indicated that Kirkwood model can be successfully used for calculation of dielectric constants of the pure fluids. The obtained dielectric constant values are compared with those reported in the literature, and are consistent with those reported in the literature.